A further test of the spectrograph is the evaluation of its potential
for the study of the hydrogen containing minerals and in particular the
vibration of the OH bonds of water and hydroxyl ions. The figure
below shows the spectrum for a hornblende crystal. A very small broad
band between 3600 and 3700 cm-1 appears, it should be the OH
stretching vibration of hydroxyl but the sharp peaks at 2700 and 2950 cm-1
are unknown. These two artifacts also appear on a gypsum spectrum below.
Their intensity is lower on the gypsum spectrum simply because the Raman
intensity of the OH band is much higher for gypsum than for hornblende.
After a few experiments, these two peaks were identified as spurious
laser lines in the UV present here in the second order of the ruled
grating. Using a red filter in front of the laser suppress completely
these lines and give a pure Raman spectrum for CH and OH region. These
lines do not appear in the plastic spectra due to the high intensity of
CH in Raman. Normally, the laser had a band pass filter in front of it
to isolate laser line but after consulting the manufacturer data sheet
of this filter, I realized that it is not efficient in the UV. So now,
the red filter is always in place when recording spectra in the range
2500 - 4000 cm-1. The last spectrum on this page is a clean
Raman spectrum of the crystal water in a gypsum with the red filter in
place.
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